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half time

Time required for the concentration of a reactant in a given reaction to reach a value that is the arithmetic mean of its initial and final (equilibrium) values. For a reactant that is entirely consumed it is the time taken for the reactant concentration to fall to one half of its initial value.

Note: The half life of a reaction has meaning only in special cases:

  1. For a first-order reaction, the half life of the reactant may be called the half life of the # For a reaction involving more than one reactant, with the concentrations of the reactants in their stoichiometric ratios, the half life of each reactant is the same, and may be called the half life of the reaction.
If the concentrations of reactants are not in their stoichiometric ratios, there are different half lives for different reactants, and one cannot speak of the half life of the reaction.

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  • Walter Lane
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